Thermal,mechanical and structural investigation of copolyimide–silica hybrids containing phosphine oxide

In this study, a novel hybrid copolyimide was synthesized from copolyamic acid solutions (PAAs) obtained by the reaction between bis(3-aminophenoxy-4-phenyl)phenylphosphine oxide (m-BAPPO), 3,3′-diaminodiphenyl sulfone (DDS) and 3,3′,4,4′-benzophenone tetracarboxylic dianhydride (BTDA), followed by thermal imidization. Hybrid materials containing 5% SiO₂ were synthesized by sol–gel technique. The polyimide–silica hybrids were characterized by Fourier Transform Infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Thermogravimetric analysis showed that the weight loss of hybrids is shifted to the higher temperature compared to the neat copolyimide. The contact angle measurements confirmed the hydrophobic surface of hybrids. Moreover, the gas permeability measurements were also done to take a step for forthcoming gas separation studies. The tensile modulus and strength of the copolyimides are good.     

Surface nanodeformations caused by ultrashort laser pulse

Ultrashort laser pulse is a unique nanometallurgical tool which operates at extreme conditions: ultimate strength of material, the smallest spatiotemporal scales, and nonequlibrium crystallization. Approaches to ultimate strength and to highly nonequlibrium crystallization are tightly coupled with the smallness of spatiotemporal scales. Usage of the tool opens new opportunities to create materials with enhanced surface hardness, anticorrosion properties, and diverted optical constants. To use these advantages we have first of all to develop clear and reliable physical model. The paper presents new results concerning interactions of optical or X-ray lasers with metals. It is shown that ultrashort laser pulse melts surface layer, sends shock into bulk, and foams molten metal. Dense dislocation bilayer is created thanks to fast recrystallization (the first sublayer) and plastic transformations behind strong shock (the second sublayer). Plastic shock generated at moderate laser intensities attenuates sharply during its propagation into metal. During this attenuation, a plastic shock regenerates into a powerful elastic shock. This process defines boundary between the second dislocation sublayer and undamaged solid. Mechanical breaking of foam after its strong stretching and fly away of a part of melt together with fast freezing are responsible for appearance of chaotic frozen nanostructures at an irradiated surface.     

Mechanical properties of graphene films enhanced by homo-telechelic functionalized polymer fillers via π–π stacking interactions

Most researches on graphene/polymer composites are focusing on improving the mechanical and electrical properties of polymers at low graphene content instead of paying attention to constructing graphene’s macroscopic structures. In current study the homo-telechelic functionalized polyethylene glycols (FPEGs) were tailored with π-orbital-rich groups (namely phenyl, pyrene and di-pyrene) via esterification reactions, which enhanced the interaction between polyethylene glycol (PEG) molecules and chemical reduced graphene oxide (RGO) sheets. The π–π stacking interactions between graphene sheets and π-orbital-rich groups endowed the composite films with enhanced tensile strength and tunable electrical conductivity. The formation of graphene network structure mediated by the FPEGs fillers via π–π stacking non-covalent interactions should account for the experimental results. The experimental investigations were also complemented with theoretical calculation using a density functional theory. Atomic force microscope (AFM), scanning electron microscope (SEM), X-ray diffraction (XRD), nuclear magnetic resonance (NMR), thermal gravimetric analysis (TGA), UV–vis and fluorescence spectroscopy were used to monitor the step-wise preparation of graphene composite films.     

An investigation into the cause of loss of containment from the supply of mini-bulk lubricants

An Intermediate Bulk Container (IBC) was punctured during its handling, releasing oil onto soil at an environmentally-sensitive region of Australia. The telehandler did not pierce the plastic of the IBC directly (as was expected) but rather one of the tynes had caught on the underside of the metal base plate, despite numerous controls being in place at time of spill, revealing a previously unreported mechanism for a fluid spill from handling of petroleum hydrocarbons. The diverse investigation team used a root cause analysis (RCA) technique to identify the underlying cause: the inspection process was inadequate with contributing factors of not using a spotter and design of IBC did not anticipate conditions. Engineering controls were put in place as part of the change management process to help prevent spills from occurring from piercing from telehandler tynes on the current project site.     

Decision support system of unplanned dilution and ore-loss in underground stoping operations using a neuro-fuzzy system

Unplanned dilution and ore-loss are the most critical challenges in underground stoping operations. These problems are the main cause behind a mine closure and directly influencing the productivity of the underground stope mining and the profitability of the entire operation. Despite being aware of the significance of unplanned dilution and ore-loss, prediction of these phenomena is still unexplained as they occur through complex mechanisms and causative factors. Current management practices primarily rely on similar stope reconciliation data and the intuition of expert mining engineers. In this study, an innovative unplanned dilution and ore-loss (uneven break: UB) management system is established using a neuro-fuzzy system. The aim of the proposed decision support system is to overcome the UB phenomenon in underground stope blasting which provides quantitative prediction of unplanned dilution and ore-loss with practical recommendations simultaneously. To achieve the method proposed, an uneven break (UB) prediction system was developed by an artificial neural network (ANN) considering 1076 datasets covering 10 major UB causative factors collected from three underground stoping mines in Western Australia. In succession, the UB consultation system was established via a fuzzy expert system (FES) in reference to surveyed results of fifteen underground-mining experts. The UB prediction and consultation system were combined as one concurrent neuro-fuzzy system that is named the ‘uneven break optimiser’. Because the current UB prediction systems in investigated mines were highly unsatisfactory with correlation coefficient (R) of 0.088 and limited to only unplanned dilution, the performance of the proposed UB prediction system (R of 0.719) is a remarkable achievement. The uneven break optimiser can be directly employed to improve underground stoping production, and this tool will be beneficial not only for underground stope planning and design but also for production management.     

Content adaptive video denoising based on human visual perception

In this paper, we propose content adaptive denoising in highly corrupted videos based on human visual perception. We introduce the human visual perception in video denoising to achieve good performance. In general, smooth regions corrupted by noise are much more annoying to human observers than complex regions. Moreover, human eyes are more interested in complex regions with image details and more sensitive to luminance than chrominance. Based on the human visual perception, we perform perceptual video denoising to effectively preserve image details and remove annoying noise. To successfully remove noise and recover the image details, we extend nonlocal mean filtering to the spatiotemporal domain. With the guidance of content adaptive segmentation and motion detection, we conduct content adaptive filtering in the YUV color space to consider context in images and obtain perceptually pleasant results. Extensive experiments on various video sequences demonstrate that the proposed method reconstructs natural-looking results even in highly corrupted images and achieves good performance in terms of both visual quality and quantitative measures.     

Exactly satisfying initial conditions neural network models for numerical treatment of first Painlevé equation

In this paper, novel computing approach using three different models of feed-forward artificial neural networks (ANNs) are presented for the solution of initial value problem (IVP) based on first Painlevé equation. These mathematical models of ANNs are developed in an unsupervised manner with capability to satisfy the initial conditions exactly using log-sigmoid, radial basis and tan-sigmoid transfer functions in hidden layers to approximate the solution of the problem. The training of design parameters in each model is performed with sequential quadratic programming technique. The accuracy, convergence and effectiveness of the proposed schemes are evaluated on the basis of the results of statistical analyses through sufficient large number of independent runs with different number of neurons in each model as well. The comparisons of these results of proposed schemes with standard numerical and analytical solutions validate the correctness of the design models.     

ML-SOR: Message routing using multi-layer social networks in opportunistic communications

Opportunistic networks are a generalization of DTNs in which disconnections are frequent and encounter patterns between mobile devices are unpredictable. In such scenarios, message routing is a fundamental issue. Social-based routing protocols usually exploit the social information extracted from the history of encounters between mobile devices to find an appropriate message relay. Protocols based on encounter history, however, take time to build up a knowledge database from which to take routing decisions. While contact information changes constantly and it takes time to identify strong social ties, other types of ties remain rather stable and could be exploited to augment available partial contact information. In this paper, we start defining a multi-layer social network model combining the social network detected through encounters with other social networks and investigate the relationship between these social network layers in terms of node centrality, community structure, tie strength and link prediction. The purpose of this analysis is to better understand user behavior in a multi-layered complex network combining online and offline social relationships. Then, we propose a novel opportunistic routing approach ML-SOR (Multi-layer Social Network based Routing) which extracts social network information from such a model to perform routing decisions. To select an effective forwarding node, ML-SOR measures the forwarding capability of a node when compared to an encountered node in terms of node centrality, tie strength and link prediction. Trace driven simulations show that a routing metric combining social information extracted from multiple social network layers allows users to achieve good routing performance with low overhead cost.     

Ultrasonic tomographic velocimeter for visualization of axial flow fields in pipes

An ultrasonic tomographic velocimeter to provide quantitative images of axial flow fields in pipes is developed and presented in this work. To detect the flow in various directions and positions, a novel transducer configuration strategy is proposed. All-in-one transducers are mounted in two sectional planes of the pipe. In each plane, N transducers are equally spaced along the circumference. Overlapped propagation paths are introduced by the configuration strategy, and the influence of the vortex flow can be eliminated theoretically by averaging the line velocities of the overlapped paths. To achieve a fast detection speed, the projection data is collected via an electrical scan in a fan-beam mode. After rearrangement and interpolation of the projection data, the parallel beam filtered back projection (FBP) algorithm is implemented to reconstruct the axial flow field. Numerical simulations with the theoretical velocity profiles were performed. The compensation method for the vortex flow is proved to be effective and necessary, and the number of transducers required for reconstruction of common flow profiles was estimated. Accordingly, an ultrasonic tomographic velocimeter consisting of 2×12 transducers was fabricated. Experiments were conducted in the straight pipe and downstream of a single bend pipe and compared with the computational fluid dynamics (CFD) simulation results. As demonstrated, the ultrasonic tomographic velocimeter was capable of visualizing both symmetric and asymmetric axial flow fields with high reliability.